Despite the headline, it sounds like they actually haven't done squat with the photovoltaic part of the system, it really doesn't talk about the light conversion part of the system at all.
Apparently what they are really saying is that they have an almost 100%-efficient USE of the photovoltaic electrical output to electrolyze H2 and O2 from water, which can then be used to run fuel cells 24/7 (or, of course, to provide H2 for a mobile combustion engine). Still pretty cool, but it involves a more elaborate composite power system, not a quantum leap in solar cell tech.